The oxidising power of H 2 O 2 has also been used for decades in homes as a treatment for minor cuts and scratches. Its oxidising properties are effective in inhibiting growth and killing microbes. What makes hydrogen peroxide unique is the foaming action that takes place whenever it is placed on a cut. Some people used to believe that this foaming action indicated the presence of infection, and that the H 2 O 2 was foaming as it got to work destroying the disease.
In reality hydrogen peroxide foams any time it comes into contact with blood, because an enzyme in blood catalyses the decomposition of H 2 O 2 to water and oxygen gas. But a benefit of the foaming action is that hydrogen peroxide acts as a cleaning agent, bringing any embedded dirt up to the surface. H 2 O 2 is present in trace amounts in honey, which is why before the advent of modern chemical preparation methods, honey used to be used for dressing wounds.
Average Mass. Monoisotopic Mass. Metabolite of Species. Mus musculus NCBI:txid Saccharomyces cerevisiae NCBI:txid Source: yeast. Escherichia coli NCBI:txid See: PubMed. Homo sapiens NCBI:txid See: DOI. Roles Classification. Chemical Role s :. Biological Role s :. Escherichia coli metabolite Any bacterial metabolite produced during a metabolic reaction in Escherichia coli. Saccharomyces cerevisiae metabolite Any fungal metabolite produced during a metabolic reaction in Baker's yeast Saccharomyces cerevisiae.
GABA antagonist A compound that inhibits the action of gamma -aminobutyric acid. These two processes are represented by the two chemical equations shown at right. Chemists use redox half-reactions to describe thermodynamic processes like the ones embodied by such equations.
For both of the reactions shown, the hydrogen molecules are oxidized and the oxygen atoms are reduced. Accordingly, each of the reactions below is described by a combination of two half-reactions--one corresponding to a chemical oxidation and another corresponding to a reduction.
The redox half-reaction for hydrogen oxidation is relatively simple and is shown on the left side of the scheme below. In this oxidation, a molecule of hydrogen gas is ionized to two electrons and two protons. Writing a half-reaction for oxygen reduction is more complicated, since oxygen can be reduced by either one, two or four electrons, as shown by the square redox scheme to the right, below.
In most chemical reactions, molecular oxygen is reduced along the red and blue pathways highlighted in this redox scheme. The selective reduction of oxygen to water in such biological systems is crucial, not only in order to maximize the energy produced for cellular metabolism but also because hydrogen peroxide is a powerful oxidant and cytotoxin, which harms living cells.
Given the energetics presented above, there is a strong thermochemical bias for the production of water over hydrogen peroxide when H 2 and O 2 are reacted together.
For instance, when hydrogen gas is burned in the presence of oxygen, a large amount of energy is released and water is produced as the major product.
0コメント